Peroxidatic oxidation of catecholamines. A kinetic electron spin resonance investigation using the spin stabilization approach.
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چکیده
منابع مشابه
MAGNETISATION AND ELECTRON SPIN RESONANCE STUDIES OF TETRAHEDRAL AMORPHOUS CARBON
The magnetisation and electron spin resonance (ESR) spectrum of two specimens of tetrahedral amorphous carbon (ta-C), deposited from a filtered cathodic arc, were measured over a wide temperature range. The magnetisation was found to consist of superparamagnetic, paramagnetic and diamagnetic contributions. The superparamagnetic contribution resembled that recently found in carbon prepared from ...
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The ESR-spin stabilization approach has been employed to detect and characterize o-semiquinone radicals from the oxidation of epinephrine and related materials (norepinephrine, 3,4-dihydroxynorephedrine, isoproterenol, and adrenalone) in aqueous solutions. Semiquinones were generated by various oxidative procedures--enzymatic oxidation (with horseradish peroxidase/H2O2), chemical oxidation (wit...
متن کاملmagnetisation and electron spin resonance studies of tetrahedral amorphous carbon
the magnetisation and electron spin resonance (esr) spectrum of two specimens of tetrahedral amorphous carbon (ta-c), deposited from a filtered cathodic arc, were measured over a wide temperature range. the magnetisation was found to consist of superparamagnetic, paramagnetic and diamagnetic contributions. the superparamagnetic contribution resembled that recently found in carbon prepared from ...
متن کاملElectron Spin Resonance
The vast majority of magnetic resonance imaging and spectroscopic investigations make use of nuclear magnetic resonance (NMR), exploiting the interactions of atomic nuclei with applied static and radiofrequency magnetic fields. Nevertheless, there exists another important “flavour” of magnetic resonance, called Electron Spin Resonance (ESR) – or, interchangeably, Electron Paramagnetic Resonance...
متن کاملElectron Spin Resonance
Quantum theory tells us electrons have certain properties such as spin. Any type of angular momentum, including spin, can be coupled with a magnetic field. Such a coupling, along with microwave spectroscopy, can be used to study specific attributes of certain types of materials. This phenomenon is exploited in electron spin resonance (ESR) microwave spectroscopy. Among the materials that can be...
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ژورنال
عنوان ژورنال: Journal of Biological Chemistry
سال: 1984
ISSN: 0021-9258
DOI: 10.1016/s0021-9258(17)42830-4